に限って details
of all times/people — ironic bad luck; also, "of all people, X would never"
今日に限って傘持ってくるの忘れたよ。
kyou ni kagitte kasa motte kuru no wasureta yo.
Of all days, I forgot to bring my umbrella today. casual
あの真面目な田中さんに限って、遅刻するはずがない。
ano majime na tanaka-san ni kagitte, chikoku suru hazu ga nai.
Of all people, someone as conscientious as Tanaka would never be late. neutral
Examples
of all times/people — ironically, the worst possible moment turns out to be exactly when something (usually undesirable) happens
今日に限って傘持ってくるの忘れたよ。
kyou ni kagitte kasa motte kuru no wasureta yo.
Of all days, I forgot to bring my umbrella today. casual
急いでいる時に限って、電車が遅れる。
isoide iru toki ni kagitte, densha ga okureru.
Wouldn't you know it, the train runs late exactly when I'm in a hurry. neutral
に限って〜ない — of all people, X would never; a categorical, trust-based denial
あの真面目な田中さんに限って、遅刻するはずがない。
ano majime na tanaka-san ni kagitte, chikoku suru hazu ga nai.
Of all people, someone as conscientious as Tanaka would never be late. neutral
弊社の社員に限って、そのような不正を行うことはございません。
heisha no shain ni kagitte, sono you na fusei o okonau koto wa gozaimasen.
None of our employees, of all people, would ever engage in that kind of misconduct. formal
Formation
{N}にかぎってattaches to noun
Related patterns
Similar
はずがない reasons from evidence to a flat "shouldn't be possible"; に限って supplies the reason for trusting this particular person or moment in the first place — あの人に限ってそんなことをするはずがない stacks the two, に限って naming who deserves the benefit of the doubt and はずがない delivering the verdict.
Lookalikes
限って singles out exactly one item and always carries an evaluative charge — bad luck, or absolute trust; 限り just states a plain boundary condition with no judgment attached, so 忙しい時に限って sighs where 生きている限り merely reports.
Same に限 root, opposite direction on identical morphology — に限らず widens a scope past N ("not just N"), while に限って narrows straight down to N, usually with an ironic sting ("of all things, N").
Both narrow the claim down to exactly one item, but に限る rates that item as the objectively BEST choice on offer, while に限って rates it as the WORST-timed coincidence (or the one person too trustworthy to doubt) — same narrowing move, opposite evaluation.